Oxide chlorine

Oxides po oxides o elemene eseese valaauina lotoa ma okesene. Toeitiiti lava elemene uma fausia e tuufaatasi. Chloro, faapea foi ma isi halogens, faamatalaina i se tuufaatasi tulaga oxidation lelei. oxides chlorine uma o mea matua mautu, o uiga mo le oxides o halogens. Fa iloa mea latou molecules aofia ai chlorine ma okesene.

1. Gaseous lotoa mai samasama e lanu lanu i se manogi uiga (manogi faamanatu kasa Cl2) - oxide chlorine (I). fua faatatau vailaau Cl2O. O le faaliusuavai tulaga o minus 116 ° C, pupuna vevela + 2 ° C. I lalo o tuutuuga masani, o lona density e tutusa ma 3,22 kg / m³.
2. Samasama po o moli-samasama kesi ma se manogi uiga - oxide chlorine (IV). ClO2 fua vailaau. O le faaliusuavai tulaga minus 59 ° C, o le tulaga pupuna faaopoopo 11 ° C.
3. Le mumu-lanu enaena suavai - oxide chlorine (VI). Cl2O6 fua vailaau. Faaliusuavai manatu faaopoopo 3,5 ° C, o le pupuna manatu faaopoopo 203 ° C.
4. suavaia Colorless suauu - oxide chlorine (VII). Cl2O7 fua vailaau. Faaliusuavai tulaga minus 91,5 ° C, o le tulaga pupuna faaopoopo 80 ° C.

tulaga oxidation chlorine Oxide +1 anhydride o acid monobasic hypochlorous vaivai (HClO). Saunia e ala i le auala o lona oxide mercuric Peluso e tali i kasa chlorine e tusa i se tasi o faamatalaga e tali: 2Cl2 + 2HgO → Cl2O + Hg2OCl2 po 2Cl2 + HgO → Cl2O + HgCl2. tafe aiaiga o nei tali eseese. oxide Chlorine (I) ua condensed i se vevela o minus 60 ° C ona i le vevela maualuga ai decomposes explosively, ma i se faiga faasagatonu o se papa. Cl2O fofo aqueous maua e chlorination i le vai po o carbonates alkali, alkaline uʻamea lalolagi. Oxide faaleaogaina foi i le vai, lea ua faia e le acid hypochlorous: Cl2O + H2O ↔ 2HClO. Gata i lea, ua soloia foi i tetrachloride carbon.

oxidation chlorine Oxide tulaga +4 ese iloa karaponi. O lenei mea sa faataapeina i le vai, sulfuric ma acids acetic, acetonitrile, carbon tetrachloride, ma isi solvents faatulagaina ma faateleina polarity lea e faateleina ai lona solubility. I totonu o le fale suesue ua saunia e le tali chlorate potassium ma acid oxalic: 2KClO3 + H2C2O4 → K2CO3 + 2ClO2 + CO2 + H2O. Talu oxide chlorine (IV) o se mea papa, e le mafai ona teuina i fofo. Mo lenei faamoemoe, o loo faaaogaina silica, i le mafai ona teuina lona luga i ClO2 pepa adsorbed mo se taimi umi, ae le mafai ona aveesea e faaleagaina ai lona mama chlorine, talu ai e le faavaivaia e le gel silica. I ClO2 tulaga tau alamanuia saunia e faaitiitia ma karaponi teio i luma o le acid sulfuric, sodium chlorate: 2NaClO3 + SO2 + H2SO4 → 2NaHSO4 + 2ClO2. O le faaaogaina o se pisia, f.t.t., pepa po o cellulose, ma isi, faapea foi mo sterilizing ma le faavailaau mea eseese.

oxidation chlorine Oxide tulaga +6, e decomposes e tusa ma le faamatalaga tali i luga o faaliusuavai: Cl2O6 → 2ClO3. oxide chlorine saunia (VI) oxidizing le karaponi osone: 2O3 + 2ClO2 → 2O2 + Cl2O6. O lenei oxide e mafai ona tali atu i tali alkaline ma le vai. I lenei tulaga o se tali disproportionation tupu. Mo se faataitaiga, e ala i tali i hydroxide potassium: 2KOH + Cl2O6 → KClO3 + KClO4 + H2O, o le taunuuga maua chlorate ma perchlorate potassium.

oxide maualuga chlorine taʻua foi chlorine po anhydride dihlorogeptaoksid o se oxidant malosi. E le o mafai ona o se pine po o se pa ina faamafanafana. Ae peitai, e sili atu fale o manu o lenei mea nai lo le oxides i le oxidation tulaga +1 ma +4. Faamalepeina ai le chlorine ma le okesene ua faatelevaveina e le afioaga o le maualalo oxides ma le tulai vevela mai le 60 i le 70 ° C. Chlorine oxide (VII) e mafai ona o lemu soluble i le vai malulu, o le tali e mafua maua acid chloric: H2O + → Cl2O7 2HClO4. Dihlorogeptaoksid saunia e malie le susunuina acid perchloric ma anhydride phosphoric: P4O10 + 2HClO4 → Cl2O7 + H2P4O11. e mafai ona maua foi Cl2O7 faaaogaina oleum nai lo le pentoxide phosphorus.

Fuaiupu kemisi inorganic, lea suesue oxides halogen, e aofia ai oxides, chlorine, sa amata ona atiina ae vave i tausaga talu ai nei, ona o le malosi matuai nei tuufaatasi. E mafai ona latou combustors vaalele malosi faaliliuina vave ma i punaoa nei vailaau e mafai ona pulea le saosaoa o ana recoil. O le isi mafuaaga mo le aia i ai - o le avanoa o synthesizing vaega fou o tuufaatasi inorganic, f.t.t., chlorine oxide (VII) o le progenitor o perchlorates.